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Hello Meresa. I believe Darpa has done some related work in the area. They've been very interested in how to keep soldiers cool, and have funded more basic work on thermoregulation.

link

Rik commented on Bigger Filter Masks to prevent overheat

If a doctor walks into the clinic wearing that thing the patient will probably jump off the table and run back into the jungle. Just kidding Anthony, couldn't resist. You are absolutely right to focus on getting rid of hot gas - I wouldn't be surprised if that is the most irritating part of being suited up.

Jay, please see the updated video on this page. I'm making jumps each day in the ability to take the whole 3D thermal envelope of suits/skin. Each measurement has 0.01C resolution, and there are 14 million measurements of just the torso in the video above.